Beilstein J. Org. Chem.2017,13, 558–563, doi:10.3762/bjoc.13.54
induced thiol–yne click reaction. Using this reaction, we could greatly enhance the CMP nanomembrane synthesis and further broaden the variability of the LbL approach.
Keywords: click chemistry; conjugated microporous polymers (CMPs); microporous materials; nanomembranes; thin films; thiol–ynecoupling
reaction (TYC); Introduction
The synthesis of microporous organic and inorganic materials such as zeolites [1], mesoporous silica [2] as well as metal-organic frameworks (MOF) [3][4] and covalent organic frameworks (COF) [5][6][7] attracted large attention because of their high potential in catalysis, gas
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Graphical Abstract
Figure 1:
LbL synthesis with TPM-SH and TPM-alkyne using light-induced TYC reaction in the presence of the ph...